岩永 哲夫(IWANAGA, Tetsuo)


TEL 086-256-9779 (ダイヤルイン)
E-mail: iwanaga(AT)chem.ous.ac.jp


【職名】   講師
【担当科目】
(学部)  有機分析化学(旧:有機分光化学) 化学プレゼンテーション 化学実験 物理化学実験 卒業研究
(大学院) 構造有機化学 コンプリヘンシブ演習 フューチャーサイエンスII 特別研究

【略歴】
学歴
職歴

【学位】
博士(理学) (九州大学 2006年)

【教育・研究の方針】
基礎実験を通して化学の素養をつけさせ,研究室配属後の卒業・特別研究を通して専門知識や技術だけでなく,コミュニケーション能力を含めた社会に通用する人材を育成するべく教育を行う.

【専門分野(キーワード)】
(大分野) 有機化学
(小分野) 構造有機化学,超分子化学,X線結晶構造解析

【研究の概要】
  • 芳香族ビスイミドを利用した新しいドナー/アクセプター型分子を開発
  • 新奇な構造を持つπ電子ユニットの開発
  • 高い光電変換効率をもつ有機太陽電池材料の開発

  • 【所属学会及び社会活動】
    日本化学会,有機合成化学協会,基礎有機化学会,有機π電子学会

    【受賞】

    【研究業績(著書・学術論文・その他)】
    著書

    学術論文(総説、解説、紀要、研究会報告等を含む)

  • T. Iwanaga, R. Tanaka, S. Toyota,
    "Introduction of an Arylethynyl Group onto Anthracene Bisimide Core for Molecular Design of New π-Conjugated Compounds",
    Chem. Lett. 2014, 43, 105-107.

  • M. Inoue, T. Iwanaga, S. Toyota,
    "Nonplanar and Dynamic Structures of 1,8-Anthrylene-Ethenylene Cyclic Dimers",
    Chem. Lett. 2013, 42, 1499-1501.

  • S. Toyota, T. Tsuya, T. Iwanaga,
    "Chemistry of Anthracene-Acetylene Oligomers XXIII. Molecular Structures and Stereochemistry of Anthracene-Diacetylene Cyclic Dimers Having Two Intraannular Alkoxy Groups",
    Bull. Chem. Soc. Jpn. 2013, 86, 1309-1316.

  • M. Yoshikawa, S. Imigi, K. Wakamatsu, T. Iwanaga, S. Toyota,
    "Chemistry of Anthracene-Acetylene Oligomers XXII. Strained and Fluxional Macrocyclic Framework of Anthracene-Diacetylene Cyclic Pentamers",
    Chem. Lett. 2013, 42, 559-561.

  • S. Toyota, D. Mamiya, R. Yoshida, R. Tanaka, T. Iwanaga, A. Orita, J. Otera,
    "Efficient Synthesis of 9,10-Bis(phenylethynyl)anthracene Derivatives by Integrated Sonogashira Coupling and Double-Elimination Reaction",
    Synthesis 2013, 45, 1060-1068.

  • T. Tsuya, T. Iwanaga, S. Toyota,
    "Chemistry of Anthracene-Acetylene Oligomers XXI. Structures and Stereochemistry of Chiral Anthracene-Acetylene Dimers with an Intraannular Alkoxy Group.",
    Bull. Chem. Soc. Jpn. 2013, 86, 138-145.

  • S. Toyota, K. Kawai, T. Iwanaga, K. Wakamatsu,
    "Tolanophane Revisited - Resolution and Racemization Mechanism of a Twisted Chiral Aromatic Compound",
    Eur. J. Org. Chem. 2012, (29), 5679-5684.

  • T. Iwanaga, K. Miyamoto, K. Tahara, K. Inukai, S. Okuhata, Y. Tobe, S. Toyota,
    "Chemistry of Anthracene-Acetylene Oligomers. XX. Synthesis, Structures, and Self-Association of Anthracene-Anthraquinone Cyclic Compounds with Ethynylene Linkers",
    Chem. Asian J. 2012, 7, 935-943.

  • K. Sako, Y. Mugishima, T. Iwanaga, S. Toyota, H. Takemura, M. Watanabe, T. Shinmyozu, M. Shiotsuka, H. Tatemitsu,
    "Synthesis and redox properties of π-conjugated 4,5-diazafluorene derivatives incorporating 9-cyanomethylene moiety as an electron acceptor.",
    Tetrahedron Lett. 2011, 52, 5865-5868.

  • T. Iwanaga, H. Ida, M. Takezaki, S. Toyota,
    "Introduction of Two Anthracene Moieties into Perylene Bisimide Core by Suzuki-Miyaura Coupling toward Construction of Donor-Acceptor-Donor Array.",
    Chem. Lett. 2011, 40, 970-971.

  • S. Toyota, H. Harada, H. Miyahara, T. Kawakami, K. Wakamatsu, T. Iwanaga,
    "Chemistry of Anthracene-Acetylene Oligomers XIX. Construction of Higher 1,8-Anthrylene-Alkynylene Macrocycles: Synthesis, Structures, and Conformational Analysis of Cyclic Hexamer and Dodecamer.",
    Bull. Chem. Soc. Jpn. 2011, 84, 829-838.

  • T. Ishikawa, T. Iwanaga, S. Toyota, M. Yamasaki,
    "Chemistry of Anthracene-Acetylene Oligomers. XVIII. Construction and Structures of Belt-Shaped Macrocyclic Oligomers with Anthracene Units and Acetylene Linkers and Resolution of Chiral Derivatives.",
    Bull. Chem. Soc. Jpn. 2011, 84, 729-740.

  • H. Takemura, A. Takahashi, H. Suga, M. Fukuda, T. Iwanaga,
    "Synthesis of Azacalixarenes through Dihydrobenzoxazine Derivatives of Phenols.",
    Eur. J. Org. Chem. 2011, (17), 3171-3177.

  • S. Toyota, T. Shimizu, T. Iwanaga, K. Wakamatsu,
    "Structures and Conformational Analysis of 1,8-Bis(9-triptycylethynyl)anthracene and Its Derivatives as Prototypes of Molecular Spur Gears.",
    Chem. Lett. 2011, 40, 312-314.

  • T. Shimo, T. Itoh, Y. Araki, T. Iwanaga, T. Shinmyozu, K. Somekawa,
    "Facile Synthesis of 3-(Succinimid-3-yl)-2-oxo-2,3-dihydroimidazo[1,2-a]pyridine Derivatives by Sequential Intra- and Intermolecular Michael Reactions between 2-Aminopyridines and Maleimides.",
    Heterocycles 2011, 83, 47-55.

  • T. Nakagaki, A. Harano, Y. Fuchigami, E. Tanaka, S. Kidoaki, T. Okuda, T. Iwanaga, K. Goto, T. Shinmyozu,
    "Molecular Tubes and Capsules, Part 6: Formation of Nanoporous Fibers by the Self-Assembly of Pyromellitic Diimide-Based Macrocycle.",
    Angew. Chem. Int. Ed. 2010, 49, 9676-9679.

  • S. Toyota, T. Kawakami, R. Shinnishi, R. Sugiki, S. Suzuki, T. Iwanaga,
    "Chemistry of Anthracene?Acetylene Oligomers. XVII. Synthesis, structure, and dynamic behavior of 1,8-anthrylene pentamers and hexamers with acetylene linkers.",
    Org. Biomol. Chem. 2010, 8, 4997-5006.

  • J.-K. Fang, D.-L. An, K. Wakamatsu, T. Ishikawa, T. Iwanaga, S. Toyota, S.-i. Akita, D. Matsuo, A. Orita, J. Otera,
    "Synthesis and spectroscopic study of phenylene-(poly)ethynylenes substituted by amino or amino/cyano groups at terminal(s): electronic effect of cyano group on charge-transfer excitation of acetylenic π-systems.",
    Tetrahedron, 2010, 66, 5479-5485.

  • K. Miyamoto, T. Iwanaga, S. Toyota,
    "Chemistry of Anthracene?Acetylene Oligomers. XVI. Influence of Conformation of 9,10-Anthrylene Rotors on Structures and Self-association Properties of Macrocyclic Arylene-Alkynylene Oligomers.",
    Chem. Lett. 2010, 39, 288-290.

  • T. Ishikawa, T. Shimasaki, H. Akashi, T. Iwanaga, S. Toyota, M. Yamasaki,
    "Chemistry of Anthracene?Acetylene Oligomers. XV. Synthesis, Structures, and Dynamic Behavior of Chiral Anthrylene?Ethynylene Cyclic Tetramers and Related Derivatives and Resolution of Enantiomers.",
    Bull. Chem. Soc. Jpn. 2010, 83, 220-232.

  • J.-K. Fang, D.-L. An, K. Wakamatsu, T. Ishikawa, T. Iwanaga, S. Toyota, D. Matsuo, A. Orita, J. Otera,
    "Synthesis and Spectroscopic Study of Diphenylamino-substituted Phenylene-(poly)ethynylenes: Remarkable Effect of Acetylenic Conjugated Modes.",
    Tetrahedron Lett. 2009, 51, 917-920.

  • S. Toyota, R. Azami, T. Iwanaga, D. Matsuo, A. Orita, J. Otera,
    "Chemistry of Anthracene?Acetylene Oligomers. XIV. Convenient Synthesis of Anthrylethynes by Double Elimination Reaction from Aldehydes and Sulfones.",
    Bull. Chem. Soc. Jpn. 2009, 82, 1287-1291.

  • H. Takemura, M. Kaneko, K. Sako, T. Iwanaga,
    "The intramolecular C-F???HO hydrogen bond of 2-fluorophenyldiphenylmethanol.",
    New J. Chem. 2009, 33, 2004-2006.

  • S. Toyota, H. Miyahara, M. Goichi, S. Yamasaki, T. Iwanaga,
    "Chemistry of Anthracene?Acetylene Oligomers. XIII. Synthesis, Structures, and Spectroscopic Properties of All Possible 1,8-Anthrylene Cyclic Tetramers with Acetylene and Diacetylene Linkers.",
    Bull. Chem. Soc. Jpn. 2009, 82, 931-945.

  • Hiroyuki Takemura, Risako Ueda, Tetsuo Iwanaga;
    "C-F・・・HO hydorogen bond in 8-fluoro-4-methyl-1-naphthol",
    J. Fluorine Chem. 2009, 130, 684-688.

  • Guoliang Mao, Akihiro Orita, Daisuke Matsuo, Takayoshi Hirate, Tetsuo Iwanaga, Shinji Toyota, Junzo Otera;
    "Synthesis and Spectroscopic Study of Silacyclyne-substituted Phenyleneethynylenes",
    Tetrahedron Lett. 2009, 50, 2860-2864.

  • Shinji Toyota, Hiroyuki Onishi, Kan Wakamatsu, Tetsuo Iwanaga;
    "Enantiopure 1,8-Anthrylene Dimer with Acetylene Linkers and an Intraannular Alkyl Group",
    Chem. Lett. 2009, 38, 350-351.

  • Shinji Toyota, Yohei Okamoto, Takeharu Ishikawa, Tetsuo Iwanaga, Masanori Yamada;
    "Molecular Structure of Chlorocycloheptane in Inclusion Compound with 9,9'-Bianthryl and Gelation during Crystallization",
    Bull. Chem. Soc. Jpn. 2009, 82, 182-186. (BCSJ Award Article From the Chemical Society of Japan) Link

  • Shinji Toyota, Hiroyuki Onishi, Yoshihiro Kawai, Takaaki Morimoto, Hiroaki Miyahara, Tetsuo Iwanaga, Kan Wakamatsu;
    "Stereogenic Motif Consisting of Rigid Ring and Intraannular Chains: Isolation and Structures of Stereoisomers of 9-Alkyl-1,8-anthrylene-Butadiynylene Cyclic Dimers",
    Org. Lett. 2009, 11, 321-324.

  • Shinji Toyoyta, Hiroaki Miyahara, Michio Goichi, Kan Wakamatsu, Tetsuo Iwanaga;
    "Chemistry of Anthracene?Acetylene Oligomers. X. Synthesis, Structures, and Properties of 1,8-Anthrylene?Alkynylene Cyclic Trimers",
    Bull. Chem. Soc. Jpn. 2008, 81, 1147-1157. (Selected Paper)

  • Tetsuro Shimo, Kenya Sato, Weidong Wang, Toru Obata, Tetsuo Iwanaga, Teruo Shinmyozu, Kenichi Somekawa;
    "Formarion of 4-Hydrocy-3-(oxan-3-yl)courmarin from Photochemical Reaction between 4-Hydroxycoumarin and 3,4-Dihydoro-2H-pyran and MO Analysis",
    Bull. Chem. Soc. Jpn. 2008, 81, 894-896.

  • Masahiko Shibahara, Motonori Watanabe, Tetsuo Iwanaga, Taisuke Matsumoto, Keiko Ideta, Teruo Shinmyozu;
    "Synthesis, Structure, and Transannular π-π Interaction of Three- and Four-Layered [3.3]Paracyclophanes",
    J. Org. Chem. 2008, 73, 4433-4442.

  • Shinji Toyota, Makoto Kuga, Akiko Takatsu, Michio Goichi, Tetsuo Iwanaga;
    "Molecular folding screen: folding and unfolding of 1,8-anthrylene-ethynylene oligomers by photochemical cycloaddition and thermal cycloreversion",
    Chem. Commun. 2008, 1323-1325.

  • Shinji Toyota, Megumi Kurokawa, Mai Araki, Kazuya Nakamura, Tetsuo Iwanaga;
    "New π-Conjugated System with a Rigid Framework of 1,8-Anthrylene-Ethynylene Cyclic Dimer and Its Monoanthraquinone Analogue",
    Org. Lett. 2007, 71, 1053-1058.

  • Tetsuro Shimo, Yuki Matsuda, Tetsuo Iwanaga, Teruo Shinmyozu, and Kenichi Somekawa;
    "Efficient 2-Amino-2-thiazolin-4-ones or 2-Iminothiazolidin-4-ones Formation from Thioureas and Maleimides under Solvent-Free Conditions",
    Heterocycles 2007, 71, 1053-1058.

  • Masahiko Shibahara, Motonori Watanabe, Tetsuo Iwanaga, Keiko Ideta, Teruo Shinmyozu;
    "Synthesis, Structure, and Transannular π-π Interaction of Multilayered [3.3]Metacyclophanes",
    J. Org. Chem. 2007, 72, 2865-2877.

  • Tetsuo Iwanaga, Ryoma Nakamoto, Mikio Yasutake, Hiroyuki Takemura, Katsuya Sako, Teruo Shinmyozu;
    "Cyclophanes within Cyclophanes: The Synthesis of a Pyromellitic Diimide-Based Macrocycle as a Structural Unit in a Molecular Tube and Its Inclusion Phenomena",
    Angew. Chem. Int. Ed. 2006, 45, 3643-3647.

  • Shinji Toyota, Fumiko Ito, Toshiyuki Yamamoto, Haruo Akashi, Tetsuo Iwanaga;
    "Absolute Configuration and Chiroptical Properties of an Enantiopure [5-Chloro-2-(dimethylaminomethyl)phenyl]phenylborane Derivatives",
    Bull. Chem. Soc. Jpn. 2006, 79, 796-798.

  • Hiroyuki Takemura, Tetsuo Iwanaga, Teruo Shinmyozu;
    "C-F・・・Rb+ Interaction in a Fluorinated Cage Compound Complex",
    Tetrahedron Lett. 2006, 47, 8989-8991.

  • Katsuya Sako, Yukiharu Mase, Yousuke Kato, Tetsuo Iwanaga, Teruo Shinmyozu, Hiroyuki Takemura, Mitsuhiro Ito, Kousuke Sasaki, Hitoshi Tatemitsu;
    "Bis(1,3-Dithiol-2-ylidene)-[3,3]paracyclophanes; Orthogonal Interaction Charge Transfer Interaction",
    Tetrahedron Lett. 2006, 47, 9151-9154.

  • Weidong Wang, Tetsuoro Shimo, Teruo Shinmyozu, Tetsuo Iwanaga, Kenichi Somekawa;
    "Solid-state Photocycloaddition of 6,6'-Dimethyl-4,4'-polymethylenedioxy-di-2-pyrones to Benzophenone",
    Heterocycles 2006, 68, 1381-1382.

  • Hiroyuki Takemura, Tetsuo Iwanaga, Teruo Shinmyozu;
    "Structure and C-H・・・π Interaction in DMF Inclusion Complexes of Homoazacalix[4]arenes",
    Tetrahedron Lett. 2005, 46, 6687-6690.

  • Tetsuro Shimo, Mitsuhito Matsushita, Weidong Wang, Tetsuo Iwanaga, Teruo Shinmyozu. Kenichi Somekawa;
    "Preferred Head-to-tail Adduct in Soli-state [2+2] Photodimerization of 2-Pyrone-5-carboxylic Acid",
    Analytical Sciences: X-ray Structure Analysis Online 2005, 21, 169-170.

  • Hiroyuki Takemura, Hiroyuki Nakamichi, Rika Nogita, Tetsuo Iwanaga, Mikio Yasutake, Teruo Shinmyozu;
    "A Comparison of Coordination Ability of Hetero Atoms: a Li+ and Na+ Selective Pyridinophane-based Cryptand",
    Tetrahedron Lett. 2003, 44, 5087-5089.



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