2017

総説

1. 'Planar Anthracene-Acetylene Frameworks as Stereogenic Motifs'
S. Toyota, H. Ikeda, T. Iwanaga
ChemPlusChem, 2017, 82(7), 957-966. Link

論文

1. 'Synthesis, structures, and properties of 2,5-dianthrylthiophene derivatives.'
S. Toyota, M. Nishiuchi, T. Iwanaga, T. Yamauchi, T. Iwanaga, M. Hasegawa,
Can. J. Chem., 2017, 95(3), 286-291. Link

2. 'Synthesis of 1,8-Anthracene-Ethenylene Cyclic Dimers and Related Compounds and Effects of Linkers on their Structures, Electronic Properties, and Dynamic Behavior'
M. Inoue, T. Iwanaga, S. Toyota
Asian J. Org. Chem., 2017, 6, 566-574. Link

2016

論文

1. 'Macrocyclic 2,7-Anthrylene Oligomers.'
Y. Yamamoto, K. Wakamatsu, T. Iwanaga, H. Sato, S. Toyota,
Chem. Asian J., 2016, 11(9), 1370-1375. Link

2. 'Intramolecular Charge-Transfer Interaction of Donor-Acceptor-Donor Arrays Based on Anthracene Bisimide.'
T. Iwanaga, M. Ogawa, T. Yamauchi, S. Toyota,
J. Org. Chem., 2016, 80(10), 4076-4080. Link

2015

論文

1. 'Synthesis and Properties of Extended π-Conjugated Compounds with 9,10-Bis(phenylethynyl)anthracene Units'
S. Toyota, S. Karashima, T. Iwanaga,
Bull. Chem. Soc. Jpn., 2015, 88(1), 192-199.  Link

2. 'Chemistry of Anthracene-Acetylene Oligomers XXIV. Theoretical Evaluation of Molecular Strain and Interactions in Anthracene-Acetylene Cyclic Oligomers by Homodesmotic Reaction Method'
S. Toyota, K. Wakamatsu, T. Kawakami, T. Iwanaga,
Bull. Chem. Soc. Jpn., 2015, 88(2), 283-291. Link

3. 'Chemistry of Anthracene-Acetylene Oligomers XXV: On-Surface Chirality of a Self-Assembled Molecular Network of a Fan-Blade-Shaped Anthracene-Acetylene Macrocycle with a Long Alkyl Chain'
T. Tsuya, K. Iritani, K. Tahara, Y. Tobe, T. Iwanaga, S. Toyota,
Chem. Eur. J., 2015, 21(14), 5520-5527. Link

4. 'エチニルアントラセン誘導体の効率合成とオリゴマー合成への応用'
豊田真司,岩永哲夫
有機合成化学協会誌, 2015, 73(4), 328-338. Link

5. 'Cramping an Alkyl Group by Rigid Macrocyclic Framework'
S. Toyota, T. Oki, M. Inoue, K. Wakamatsu, T. Iwanaga,
Chem. Lett., 2015, 44(7), 978-980. Link

6. 'Structures, Dynamic Behavior, and Spectroscopic Properties of 1,8-Anthrylene-Ethenylene Cyclic Dimers and Their Substituent Effect.'
M. Inoue, T. Iwanaga, S. Toyota,
Bull. Chem. Soc. Jpn., 2015, 88(11), 1591-1602. Link

7. 'Enantiopure 5,5’-Bitetracene'
S. Toyota, R. Miyaji, Y. Yamamoto, M. Inoue, K. Wakamatsu, T. Iwanaga,
Eur. J. Org. Chem., 2015, (35), 7648-7651. Link

8. 'Efficient Synthesis and Electronic Spectra of Unsymmetrical 5,12-Diethynyltetracene Derivatives.'
T. Iwanaga, Y. Yamamoto, K. Nishioka, S. Toyota,
Synthesis, 2015, 47(24), 3997-4007. Link

2014

論文

1. 'Introduction of an Arylethynyl Group onto Anthracene Bisimide Core for Molecular Design of New π-Conjugated Compounds'
T. Iwanaga, R. Tanaka, S. Toyota
Chem. Lett., 2014, 43(1), 105-107. Editor's Choice

2. 'Synthesis of 2,9-Diethynylanthracene Derivatives'
S. Toyota, T. Kawakami, T. Iwanaga,
Synthesis, 2014, 46(12), 1667-1673. Link

著書

1. 'Three-Dimensional Aromatic Networks'
S. Toyota, T. Iwanaga
Top. Curr. Chem., 2014, 350, 111-140. Abstract

2013

論文

1 'Chemistry of Anthracene-Acetylene Oligomers. XXI. Structures and Stereochemistry of Chiral Anthracene?Acetylene Dimers with an Intra-Annular Alkoxy Group'
T. Tsuya, T. Iwanaga, S. Toyota
Bull. Chem. Soc. Jpn., 2013, 86(1), 138-145. Abstract

2 'Efficient Synthesis of 9,10-Bis(phenylethynyl)anthracene Derivatives by Integration of Sonogashira Coupling and Double-Elimination Reactions'
S. Toyota, D. Mamiya, R. Yoshida, R. Tanaka, T. Iwanaga, A. Orita, J. Otera,
Synthesis, 2013, 45(8), 1060-1068. Abstract

3 'Chemistry of Anthracene-Acetylene Oligomers. XXII. Strained and Fluxional Macrocyclic Framework of Anthracene-Diacetylene Cyclic Pentamers''
M. Yoshikawa, S. Imigi, K. Wakamatsu, T. Iwanaga, S. Toyota
Chem. Lett., 2013, 42(5), 559-561. Abstract

4. 'Chemistry of Anthracene?Acetylene Oligomers XXIII. Molecular Structures and Stereochemistry of Anthracene-Diacetylene Cyclic Dimers Having Two Intraannular Alkoxy Groups'
S. Toyota, T. Tsuya, T. Iwanaga
Bull. Chem. Soc. Jpn., 2013, 86(11), 1309-1316. Abstract

5. 'Nonplanar and Dynamic Structures of 1,8-Anthrylene?Ethenylene Cyclic Dimers'
M. Inoue, T. Iwanaga, S. Toyota
Chem. Lett., 2013, 42(12), 1499-1501. Abstract

2012

論文

1 'Construction of novel molecular architectures from anthracene units and acetylene linkers'
S. Toyota
Pure Appl. Chem., 2012, 84(4), 917-929. Abstract

2 'Chemistry of Anthracene-Acetylene Oligomers XX: Synthesis, Structures, and Self-Association of Anthracene-Anthraquinone Cyclic Compounds with Ethynylene Linkers'
T. Iwanaga, K. Miyamoto, K. Tahara, K. Inukai, S. Okuhata, Y. Tobe, S. Toyota
Chem. -Asian J., 2012, 7(5), 935-943. Abstract

3'Tolanophane Revisited - Resolution and Racemization Mechanism of a Twisted Chiral Aromatic Compound'
S. Toyota, K. Kawai, T. Iwanaga, K. Wakamatsu,
Eur. J. Org. Chem., 2012, (29), 5679-5684. Abstract

2011

論文

1 'Structures and Conformational Analysis of 1,8-Bis(9-triptycylethynyl)anthracene and Its Derivatives as Prototypes of Molecular Spur Gears.'
S. Toyota, T. Shimizu, T. Iwanaga, K. Wakamatsu
Chem. Lett., 2011, 40(3), 312-314. Abstract

2 'Chemistry of Anthracene?Acetylene Oligomers. XVIII. Construction and Structures of Belt-Shaped Macrocyclic Oligomers with Anthracene Units and Acetylene Linkers and Resolution of Chiral Derivatives'
T. Ishikawa, T. Iwanaga, S. Toyota, M. Yamasaki
Bull. Chem. Soc. Jpn., 2011, 84(7), 729-740. Selected Paper, Abstract

3 'Chemistry of Anthracene-Acetylene Oligomers. XIX. Construction of Higher 1,8-Anthrylene-Alkynylene Macrocycles: Synthesis, Structures, and Conformational Analysis of Cyclic Hexamer and Dodecamer'
S. Toyota, H. Harada, H. Miyahara, T. Kawakami, K. Wakamatsu, T. Iwanaga
Bull. Chem. Soc. Jpn., 2011, 84(8), 829-838. BCSJ Award Article

4 'Introduction of Two Anthracene Moieties into Perylenebis(dicarboximide) Core by Suzuki-Miyaura Coupling toward Construction of Donor-Acceptor-Donor Arrays'
T. Iwanaga, H. Ida, M. Takezaki, S. Toyota
Chem. Lett., 2011, 40(9), 740-741. Abstract

総説

1 How to Construct Chiral Macrocycles from Anthracene Units and acetylene Linkers.
S. Toyota
Chem. Lett., 2011, 40(1), 12-18. Abstract

2010

論文

1 Synthesis and Spectroscopic Study of Diphenylamino-substituted Phenylene-(poly)ethynylenes: Remarkable Effect of Acetylenic Conjugated Modes.
J.-K. Fang, D.-L. An, K. Wakamatsu, T. Ishikawa, T. Iwanaga, S. Toyota, D. Matsuo, A. Orita, J. Otera
Tetrahedron Lett., 2010, 51, 917-920. Abstract

2 Chemistry of Anthracene-Acetylene Oligomers. XV. Synthesis, Structures, and Dynamic Behavior of Chiral Anthrylene?Ethynylene Cyclic Tetramers and Related Derivatives and Resolution of Enantiomers.
T. Ishikawa, T. Shimasaki, H. Akashi, T. Iwanaga, S. Toyota, M. Yamasaki
Bull. Chem. Soc. Jpn., 2010, 83, 220-232. BCSJ Award Article

3 Chemistry of Anthracene-Acetylene Oligomers. XVI. Influence of Conformation of 9,10-Anthrylene Rotors on Structures and Self-association Properties of Macrocyclic Arylene-Alkynylene Oligomers.
K. Miyamoto, T. Iwanaga, S. Toyota
Chem. Lett., 2010, 39, 288-290. Abstract

4 Synthesis and spectroscopic study of phenylenee(poly)ethynylenes substituted by amino or amino/cyano groups at terminal(s): electronic effect of cyano group on charge-transfer excitation of acetylenic p-systems.
J.-K. Fang, D.-L. An, K. Wakamatsu, T. Ishikawa, T. Iwanaga, S. Toyota, S. Akita, D. Matsuo, A. Orita, J. Otera
Tetrahedron, 2010, 66, 5479-5485. Abstract

5 Chemistry of Anthracene-Acetylene Oligomers. XVII. Synthesis, structure, and dynamic behavior of 1,8-anthrylene pentamers and hexamers with acetylene linkers.
S. Toyota, T. Kawakami, R. Shinnishi, R. Sugiki, S. Suzuki, T. Iwanaga
Org. Biomol. Chem., 2010, 8, 4997-5006. Abstract

総説

1 Rotational Isomerism Involving Acetylene Carbon.
S. Toyota
Chem. Rev., 2010, 110, 5398-5424. Abstract

著書等

1 76. 水素雰囲気下での薗頭反応,84. 二重脱離反応によるアルキン合成
豊田真司,岩永哲夫
使える!有機合成反応241実践ガイド,丸岡啓二,野崎京子,石井康敬,大寺純蔵,富岡 清編著,化学同人,京都,2010年, pp 152-153, 168-169.

2009

論文

1 Stereogenic Motif Consisting of Rigid Ring and Intraannular Chains: Isolation and Structures of Stereoisomers of 9-Alkyl-1,8-anthrylene-butadiynylene Cyclic Dimers.
S. Toyota, H. Onishi, Y. Kawai, T. Morimoto, H. Miyahara, T. Iwanaga, K.Wakamatsu
Org. Lett., 2009, 11, 321-324.

2 Molecular Structure of Chlorocycloheptane in Inclusion Compound with 9,9'-Bianthryl and Gelation during Crystallization.
S. Toyota, Y. Okamoto, T. Ishikawa, T. Iwanaga, M. Yamada
Bull. Chem. Soc. Jpn., 2009, 82, 182-186. BCSJ Award Article

3 Ecotoxicity of the degradation products of triphenylborane pyridine (TPBP) antifouling agent
H. Okamura, S. Kitano, S. Toyota, H. Harino, K.V. Thomas
Chemosphere, 2009, 74, 1275-1278.

4 Synthesis and spectroscopic study of silacyclyne-substituted phenyleneethynylenes
G. Mao, A. Orita, D. Matsuo, T. Hirate, T. Iwanaga, S. Toyota, J. Otera
Tetrahedron Lett., 2009, 50, 2860-2864.

5 Chemistry of Anthracene-Acetylene Oligomers XII. Enantiopure 1,8-Anthrylene Dimer with Acetylene Linkers.
S. Toyota, H. Onishi, K. Wakamatsu, T. Iwanaga
Chem. Lett., 2009, 38, 350-351.

6 Chemistry of Anthracene-Acetylene Oligomers XIII. Synthesis, Structures, and Spectroscopic Properties of All Possible 1,8-Anthrylene Cyclic Tetramers with Acetylene and Diacetylene Linkers.
S. Toyota, H. Miyahara, M. Goichi, S. Yamasaki, T. Iwanaga
Bull. Chem. Soc. Jpn., 2009, 82, 931-945. BCSJ Award Article

7 Chemistry of Anthracene-Acetylene Oligomers XIV. Convenient Synthesis of Anthrylethynes by Double Elimination Reaction from Aldehydes and Sulfones.
S. Toyota, R. Azami, T. Iwanaga, D. Matsuo, A. Orita, J. Otera
Bull. Chem. Soc. Jpn., 2009, 82,1287-1291.

2008

論文

1 Structures and Inclusion Properties of Racemic and Enantiopure Dimethyl and Diphenyl 9,9'-Bianthryl-2,2'-dicarboxylates.
S. Toyota, T. Shimasaki, S. Hirano, M. Kuga, F. Toda, Chirality, 2008, 19, 295-300. Abstract

2 Molecular folding screen: folding and unfolding of 1,8-anthrylene-ethynylene oligomers by photochemical cycloaddition and thermal cycloreversion.
S. Toyota, M. Kuga, A. Takatsu, M. Goichi, T. Iwanaga,
Chem. Commun., 2008, 1323-1325.

3 Chemistry of Anthracene-Acetylene Oligomers IX. Enantiopure Anthrylene-Ethynylene Cyclic Tetramer and Racemization via Rotation of Anthracene Unit about Acetylenic Axes.
T. Ishikawa, T. Shimasaki, H. Akashi, S. Toyota,
Org. Lett., 2008, 10, 417-420 Abstract

4 Chemistry of Anthracene?Acetylene Oligomers X. Synthesis, Structures, and Properties of 1,8-Anthrylene?Alkynylene Cyclic Trimers
S. Toyota, H. Miyahara, M. Goichi, K. Wakamatsu, T. Iwanaga
Bull. Chem. Soc. Jpn., 2008, 81 , 1147-1157. Selected Paper.

著書等

1 有機化学演習ー基本から大学院入試までー
山本学,伊与田正彦,豊田真司 著,東京化学同人, 2008年 Link